基于Legendre多项式的锂离子电池降阶模型

在Newman模型以及单粒子模型(SPM)的基础上,提出基于Legendre正交多项式的电池模型降阶算法;同时,将固液相物理量的分布纳入模型算法,在提高运算速度的情况下,保证运算精度。以磷酸铁锂(Li Fe PO4)正极锂离子电池为例,对导出的降阶模型进行仿真验证。与全阶模型相比,该模型所计算的电池状态量误差均能保持在2%下。     

Proper Orthogonal Decomposition and Statistical Analysis of 2D Confined Impinging Jets Chaotic Flow

Proper orthogonal decomposition (POD) is shown to be a statistical operation that identifies the main characteristics of chaotic flows and separates them into a few modes. The dynamic chaotic flow is obtained from two‐dimensional (2D) computational fluid dynamics simulations, for different Reynolds numbers, of a confined impinging jets mixer. POD enables reconstruction of the dynamic flow from a few modes that are related to coherent flow structures. The POD flow reconstruction enables a large compression of the flow data set. The decomposition of the flow field into orthogonal modes related to coherent structures provides direct insight into the mixing dynamics and scales which are not accessible from flow dynamics statistic quantities, which were introduced in the context of turbulence and are here applied to chaotic flow.     

Thermodynamic properties of sodium pyrovanadate (Na4V2O7) at high temperature (298.15–873 K)

The sodium pyrovanadate (Na₄V₂O₇) powder was synthesized by solid-state reaction using sodium carbonate (Na₂CO₃) and vanadium pentoxide (V₂O₅) as raw materials. X-ray powder diffraction (XRD), scanning electron microscope (SEM), and differential scanning calorimeter (DSC) were used to accurately characterize the synthesized sample. The solid-state phase transformation from α-Na₄V₂O₇ to β-Na₄V₂O₇ occurs at the temperature 696 K and the enthalpy is equals to 1.03 ± 0.01 kJ/mol, the endothermic effect at 931 K and the enthalpy is equals to 31.35 ± 0.31 kJ/mol, which is related to the melting of Na₄V₂O₇. The high-temperature heat capacity of Na₄V₂O₇ was measured using a Multi-high temperature calorimeter 96 line and DSC. The obtained high-temperature heat capacity of Na₄V₂O₇, as a function of temperature, was modeled as: Cp=314.62+0.05T-5494390T^-2 J·mol^-1·K^-1 (298.15-873 K). The temperature dependence on heat capacity was then used for computing changes in the enthalpy, entropy, and Gibbs free energy at the specific temperature internal.     

Cyclodextrin-Based Multistimuli-Responsive Supramolecular Assemblies and Their Biological Functions

Cyclodextrins (CDs), which are a class of cyclic oligosaccharides extracted from the enzymatic degradation of starch, are often utilized in molecular recognition and assembly constructs, primarily via host–guest interactions in water. In this review, recent progress in CD-based supramolecular nanoassemblies that are sensitive to chemical, biological, and physical stimuli is updated and reviewed, and intriguing examples of the biological functions of these nanoassemblies are presented, including pH- and redox-responsive drug and gene delivery, enzyme-activated specific cargo release, photoswitchable morphological interconversion, microtubular aggregation, and cell–cell communication, as well as a geomagnetism-controlled nanosystem for the suppression of tumor invasion and metastasis. Moreover, future perspectives and challenges in the fabrication of intelligent CD-based biofunctional materials are also discussed at the end of this review, which is expected to promote the translational development of these nanomaterials in the biomedical field.     

Evaluation of orthogonal and biorthogonal wavelets for video steganography

ABSTRACT

In recent years, information security over the internet has gained enormous immersion due to a technological escalation in communication via digital media. Nowadays, videos are the most common form of media over the internet, and they have gained the attention of video steganography research community for the security of the communication. This paper implemented video steganography using a widely-known transform technique, discrete wavelet transform (DWT) which consists of different orthogonal and biorthogonal filters used for the decomposition of a frame/image. The aim of this paper is to provide a comparative evaluation for orthogonal and biorthogonal DWT filters with different matrices such as MSE, PSNR. The performance of the different filters has been evaluated both quantitatively and qualitatively to investigate the best among them. Also, the best of orthogonal and biorthogonal filters have been further evaluated with other metrics such as SSIM, BER and histogram analysis. Further, the embedding algorithm has been compared with the existing video steganography techniques. The experimental results illustrate that bior 6.8 (biorthogonal filter) outperforms the other orthogonal and biorthogonal filters in terms of visual distortion.     

Construction of a polynomial invariant annihilation attack of degree 7 for T-310

Abstract

Cryptographic attacks are typically constructed by black-box methods and combinations of simpler properties, for example in [Generalised] Linear Cryptanalysis. In this article, we work with a more recent white-box algebraic-constructive methodology. Polynomial invariant attacks on a block cipher are constructed explicitly through the study of the space of Boolean polynomials which does not have a unique factorisation and solving the so-called Fundamental Equation (FE). Some recent invariant attacks are quite symmetric and exhibit some sort of clear structure, or work only when the Boolean function is degenerate. As a proof of concept, we construct an attack where a highly irregular product of seven polynomials is an invariant for any number of rounds for T-310 under certain conditions on the long term key and for any key and any IV. A key feature of our attack is that it works for any Boolean function which satisfies a specific annihilation property. We evaluate very precisely the probability that our attack works when the Boolean function is chosen uniformly at random.     

汽车悬架球头拉杆冷成形技术

为提高生产效率、改变原来通过车削加工汽车悬架球头拉杆的方式,提出了一种球头拉杆的多工位冷镦成形工艺。基于DEFORM-3D软件建立了有限元模型,对球头拉杆的塑性成形过程进行了仿真,研究了预成形凸模入模角α、预成形凹模圆角R1、终成形凹模圆角R2以及终成形凹模入模角β等工艺参数对球头拉杆成形的影响,并进行了正交试验,以模具在球头拉杆成形过程中所受载荷及工件损伤值为优化目标,获得了合理的工艺参数组合。结果表明:在保证工件成形质量及模具寿命的前提下,当预成形凸模入模角α为30°、预成形凹模圆角R1为12 mm、终成形凹模圆角R2为3 mm、终成形凹模入模角β为60°时,模具载荷及工件损伤有显著的降低。采用优化后的参数进行试模生产,工件成形质量较好,验证了模拟结果的可信性,能够有效地指导工艺设计人员的设计工作。     

英语修辞问句的构成及其话语和语篇功能简析

英语修辞问句，以主谓倒装的疑问句结构形式出现，句末可以使用问号，句号或感叹号，其本质上不要求读者或听众提供答案，而是起特定的话语或篇章修辞效果。这些效果包括吸引读者或听众的注意力，激发对方的兴趣，获取对方的支持，充当模糊限定语，加强语势，突出重点，强调前述论点，提起新的话轮，回答问题等。对英语修辞问句语篇功能的了解，有助于提高英语学习者的阅读和理解能力。     

Finite-time decentralized adaptive neural constrained control for interconnected nonlinear time-delay systems with dynamics couplings among subsystems

The problem of finite-time decentralized neural adaptive constrained control is studied for large-scale nonlinear time-delay systems in the non-affine form. The main features of the considered system are that 1) unknown unmatched time-delay interactions are considered, 2) the couplings among the nested subsystems are involved in uncertain nonlinear systems, 3) based on finite-time stability approach, asymmetric saturation actuators and output constraints are studied in large-scale systems. First, the smooth asymmetric saturation nonlinearity and barrier Lyapunov functions are used to achieve the input and output constraints. Second, the appropriately designed Lyapunov-Krasovskii functional and the property of hyperbolic tangent functions are used to deal with the unknown unmatched time-delay interactions, and the neural networks are employed to approximate the unknown nonlinearities. Note that, due to unknown time-delay interactions and the couplings among subsystems, the controller design is more meaningful and challenging. At last, based on finite-time stability theory and Lyapunov stability theory, a decentralized adaptive controller is proposed, which decreases the number of learning parameters. It is shown that the designed controller can ensure that all closed-loop signals are bounded and the tracking error converges to a small neighborhood of the origin. The simulation studies are presented to show the effectiveness of the proposed method.     

Simplified model for particle collision related to attrition in pneumatic conveying

This paper presents a simple method for predicting particle attrition during pneumatic conveying. The model calculates the changes in the particle size during pneumatic conveying (as a result of the collisions between the particles and bend walls) by using empirical correlations for both the machine and material functions. The method does not require the use of complicated simulations such as DEM–CFD. Furthermore, the computational model was written in MATLAB, and the results agree well with the experimental results for salt particles. The computation time was very short: a few seconds for the first collision (particles passed through one bend), and below one minute for six collisions. The experimental results and parametric study show that higher bend radius ratios caused less damage to the conveyed material. Moreover, higher air velocities and larger pipe diameters caused more damage to the conveyed material.